Carbonized soybean hull as a replacement for carbon black in tire sidewalls

Many industries are lookingfor sustainable alternatives tosynthetic filler products thatstem from fossil fuels. Currently,carbon black enjoys the lion’sshare of filler usage in the world.It has excellent reinforcing properties, provides UV protectionand is easier to process thanother types of fillers.

Unfortunately, the cost of carbon black is indexed to the price of oil, so natural disasters, oil shortages and political strife can cause economic swings that can be detrimental to the rubber industry. Carbon black also is governed by EPA regulations restricting NOx and SOx emissions that dictate how many emissions each plant is allowed to produce, which in recent history shuttered some plants for months at a time, creating supply issues.

Carbon black is produced from oil that has polyaromatic hydrocarbons (PAH’s) on its surface, which makes it a carcinogen, increasing the likelihood of further regulations down the road. Many rubber manufacturers are looking for sustainable filler options that do not carry health risks. If carbonizing soybean hulls in a nitrogen atmosphere is successful, this could lead to a new sustainable filler that could compete with carbon black and increase the need for soybean farm production in North America without impacting the food supply, since the soybean hull is what is left over after the soybean has been harvested.

Many companies have successfully pyrolyzed carbon black from used tires and are selling this recycled black to the market. However, the reinforcing properties of pyrolyzed black are low, which limits where and how it can be used.

Recently, it has come to light that salmon die-off in the western U.S. may be attributed to common tire tread antioxidants/ antiozonants TMQ and 6ppd. If these antidegradents see future regulations, this may dramatically limit the pool of tires available for recycle.

Work has been done in Japan at the Tsuruoka National College of Technology to use carbonized soybean hulls to increase the conductivity in rubber compounds. The paper is called “Electromagnetic Shielding in Rubber Composite Materials with Soy Hull Carbon Particles.”